Music set the tone for this effortlessly chic wedding at the bride’s family winery in the rolling hills of Santa Ynez. With the Arctic Monkeys’ frontman—and best man—serenading the couple, and friends coming together to form a one-night-only supergroup, the celebration was as unforgettable as it was unique.

The groom is the rocker, the bride, an ER doctor—a perfect harmony of passion and purpose.